有机化学 ›› 2017, Vol. 37 ›› Issue (5): 1139-1159.DOI: 10.6023/cjoc201612011 上一篇    下一篇

综述与进展

手性金属有机化合物催化丙交酯聚合反应研究进展

赵宁   

  1. 陕西科技大学化学与化工学院 西安 710021
  • 收稿日期:2016-12-04 修回日期:2017-01-17 发布日期:2017-01-20
  • 通讯作者: 赵宁 E-mail:zhaoninghg@sust.edu.cn

Progress in Ring Opening Polymerization of Lactides Catalyzed by Chiral Organometallic Complexes

Zhao Ning   

  1. College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an 710021
  • Received:2016-12-04 Revised:2017-01-17 Published:2017-01-20
  • Contact: 10.6023/cjoc201612011 E-mail:zhaoninghg@sust.edu.cn

聚丙交酯因其具有良好的生物相容性、生物可降解性和可再生性,近年来引起了人们的广泛关注.利用手性金属有机化合物催化丙交酯的立体选择性开环聚合反应成为该研究的热点之一.主要介绍了手性金属有机化合物催化丙交酯开环聚合反应的研究进展.

关键词: 手性金属有机化合物, 催化, 丙交酯聚合反应

Polylactides have received considerable attention in recent years due to their outstanding properties such as biocompatibility, biodegradability, and renewability. In particular, the studies on ring opening polymerization (ROP) of lactides in stereoselective manner catalyzed by chiral organometallic complexes have been regarded as one of the most significant fields in the synthesis of polylactides. The important advances in the ROP of lactides catalyzed by chiral organometallic complexes are reviewed in this article.

Key words: chiral organometallic complexes, catalysis, polymerization of lactides