有机化学 ›› 2018, Vol. 38 ›› Issue (5): 999-1008.DOI: 10.6023/cjoc201711037 上一篇    下一篇

综述与进展

自由基正离子盐促进的化学转化研究进展

侯文涛a, 贾晓东a,b   

  1. a 西北师范大学化学化工学院 兰州 730070;
    b 扬州大学化学化工学院 扬州 225002
  • 收稿日期:2017-11-21 修回日期:2017-11-21 发布日期:2018-01-03
  • 通讯作者: 贾晓东,E-mail:jiaxd1975@163.com E-mail:jiaxd1975@163.com
  • 基金资助:

    国家自然科学基金(Nos.21362030,21562038)资助项目.

Recent Progress in Radical Cation Salts Promoted Chemical Transformations

Hou Wentaoa, Jia Xiaodonga,b   

  1. a College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070;
    b School of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002
  • Received:2017-11-21 Revised:2017-11-21 Published:2018-01-03
  • Contact: 10.6023/cjoc201711037 E-mail:jiaxd1975@163.com
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 1362030, 21562038).

自由基正离子盐早在一百多年前就被制备出来,近年来,随着自由基化学的复兴,自由基正离子盐促进的有机化学转化受到了广泛地关注.在早期的研究中,自由基正离子盐主要被用于单电子氧化反应,可以高效地实现环加成、碎裂、重排等反应.与此同时,近期的研究表明,自由基正离子盐还可以促进C—H键的需氧氧化,实现一系列C—H键的直接官能团化反应.本综述按照自由基正离子盐促进的反应类型,总结了这一领域的最新进展.

关键词: 自由基正离子盐, 单电子氧化, 碳氢活化, 环加成

The first radical cation salt (RCS) was prepared more than 100 years ago, and with the recent renaissance of radical chemistry, the RCS promoted organic transformations attrack extensively attention. In early research, RCS was mainly used to initiate single electron oxidation reactions, such as cycloaddition, fragmentation, rearrangement and so on. Recently, RCS was used to induce the aerobic oxidation of C—H bond, and achieved a series of direct functionalization of C—H bond. In this review, prominent examples from the recent literatures are organized on the basis of the different reactions enabled by RCS catalysis.

Key words: radical cation salt, single electron oxidation, C—H activation, cycloaddition