有机化学 ›› 2020, Vol. 40 ›› Issue (2): 339-350.DOI: 10.6023/cjoc201909024 上一篇    下一篇

所属专题: 有机光催化虚拟合辑

综述与进展

光催化有机物偶联/芳构化放氢反应研究进展

陈锋, 陈浩, 吴庆安, 罗书平   

  1. 浙江工业大学化学工程学院 绿色化学合成技术国家重点实验室培育基地 杭州 310014
  • 收稿日期:2019-09-16 修回日期:2019-10-18 发布日期:2019-11-01
  • 通讯作者: 罗书平 E-mail:Luoshuping@zjut.edu.cn
  • 基金资助:
    国家自然科学基金(No.21376222)和浙江省自然科学基金(No.LY18B060011)资助项目.

Progress on the Photocatalytic Organic Hydrogen-Evolution Coupling/Aromatization Reaction

Chen Feng, Chen Hao, Wu Qing'an, Luo Shuping   

  1. State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014
  • Received:2019-09-16 Revised:2019-10-18 Published:2019-11-01
  • Supported by:
    Project supported by the National Natural Science Foundation of China (No. 21376222) and the Natural Science Foundation of Zhejiang Province (No. LY18B060011).

光催化氧化还原反应具有绿色、高效、安全等优势,已经在有机化学中得到广泛关注.介绍了基于光催化的偶联/芳构化放氢反应,通过使用光催化剂/催化剂的双催化体系,可用于光催化有机碳-碳和碳-杂原子成键反应,且反应中氢气是唯一的副产物.强调了有机光氧化还原体系的构建与催化机理.

关键词: 光催化, 有机物放氢反应, 偶联反应, 芳构化反应

The photocatalytic redox reactions have been widely concerned in organic chemistry due to their green, efficiency and safety. In this review, the cross-coupling/aromatization reactions are described based on photocatalytic organic hydrogen-evolution, which can be used to build organic carbon-carbon and carbon-heteroatom bonds by using a photocatalyst/catalyst dual catalytic system. Hydrogen is the only by-product in these reactions. The system and catalytic mechanisms of organic photocatalytic redox reaction are highlighted.

Key words: photocatalysis, organic hydrogen-evolution reaction, coupling reaction, aromatization reaction