Chin. J. Org. Chem. ›› 1997, Vol. 17 ›› Issue (1): 53-56. Previous Articles     Next Articles

Original Articles

钯催化剂于外向环双键立体选择合成上之应用

罗芬台   

  1. 台北中央研究院化学研究所
  • 发布日期:1997-02-25

Synthesis of stereoselective exocyclic double bonds by the use of palladium catalysts

LUO FENTAI   

  • Published:1997-02-25

Various kinds of stereodefined exocyclic double bonds through the use of intramolecular insertion of adjacent unsaturated ligands and the following cross coupling reactions by the aid of palladium complexes were reported. A potentially versatile and highly regio- and stereoselective method for preparing α-alkylidene of γ-lactones is also described.

Key words: PALLADIUM, STEREOSELECTIVITY, CATALYST

CLC Number: