Palladium Catalyzed Decarboxylative Alkylation

Chin. J. Org. Chem. ›› 2011, Vol. 31 ›› Issue (12): 2181-2187. Previous Articles Next Articles

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钯催化的脱羧基烷基化反应

周其忠*^,1，张斌^1,2，陈丹¹，陈仁尔¹，蒋华江*^,1

(¹台州学院化学系台州 317000)
(²浙江工业大学药学院杭州 310014)

收稿日期:2011-02-22 修回日期:2011-06-13 发布日期:2011-09-02
通讯作者: 周其忠 E-mail:qizhongchou@yahoo.com

Palladium Catalyzed Decarboxylative Alkylation

Zhou Qizhong*^,1 Zhang Bin^1,2 Chen Dan¹ Chen Rener¹ Jiang Huajiang*^,1

(¹Department of Chemistry, Taizhou University, Taizhou 317000)
(²College of Pharmacy, Zhejiang University of Technology, Hangzhou 310014)

Received:2011-02-22 Revised:2011-06-13 Published:2011-09-02
Contact: ZHOU Qi-Zhong E-mail:qizhongchou@yahoo.com

Palladium catalyzed decarboxylative alkylation is an effective way to construct carbon-carbon bond especially chiral center with high catalytic activity, mild reaction conditions and good enantioselectivi- ty. In recent years, great achievements have been obtained in this field. This paper summarizes palladium catalyzed decarboxylative alkylation and mainly focuses on enantioselective Tsuji reaction and its utility in natural product synthesis in recent 5 years.

Key words: palladium catalysis, decarboxylation, allylation, benzylation, enantioseletivity

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ZHOU Qi-Zhong, ZHANG Bin, CHEN Dan, CHEN Ren-尔, JIANG Hua-Jiang. Palladium Catalyzed Decarboxylative Alkylation[J]. Chin. J. Org. Chem., 2011, 31(12): 2181-2187.

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钯催化的脱羧基烷基化反应

Palladium Catalyzed Decarboxylative Alkylation

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