Pt/WO3/ZrO2-Catalyzed Selective Hydrogenolysis of Glycerol to Produce 1,3-Propanediol

doi:10.6023/cjoc201610002

Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (3): 753-758.DOI: 10.6023/cjoc201610002 Previous Articles Next Articles

Notes

Pt/WO₃/ZrO₂催化甘油选择性氢解制备1,3-丙二醇

仝庆^a,b, 高强^a, 许波连^a, 俞磊^a,b,c, 范以宁^a,b

a 介观化学教育部重点实验室南京大学化学化工学院南京 210093;
b 南京大学扬州化学化工研究院扬州 211400;
c 扬州大学化学化工学院扬州 225002

收稿日期:2016-10-01 修回日期:2016-11-16 发布日期:2016-11-29
通讯作者: 俞磊,E-mail:yulei@yzu.edu.cn;范以宁,E-mail:ynfan@nju.edu.cn E-mail:yulei@yzu.edu.cn;ynfan@nju.edu.cn
基金资助:
国家自然科学基金（No.21202141）、江苏省高校优势学科和扬州市自然科学基金重大科技专项（No.YZ20122029）资助项目.

Pt/WO₃/ZrO₂-Catalyzed Selective Hydrogenolysis of Glycerol to Produce 1,3-Propanediol

Tong Qing^a,b, Gao Qiang^a, Xu Bolian^a, Yu Lei^a,b,c, Fan Yining^a,b

a Key Laboratory of Mesoscopic Chemistry of Ministry of Education, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093;
b Nanjing University-Yangzhou Chemistry and Chemical Engineering Institute, Yangzhou 211400;
c School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002

Received:2016-10-01 Revised:2016-11-16 Published:2016-11-29
Contact: 10.6023/cjoc201610002 E-mail:yulei@yzu.edu.cn;ynfan@nju.edu.cn
Supported by:
Project supported by the National Natural Science Fundation of China (No. 21202141), the Priority Academic Program Development of Jiangsu Higher Education Institutions, and the Key Science & Technology Specific Projects of Yangzhou (No. YZ20122029).

1. Pt/WO₃/ZrO₂-Catalyzed Selective Hydrogenolysis of Glycerol to Produce 1,3-Propanediol.PDF(250KB)

Abstract

Glycerol is an abundantly generated biomass and conversion of this compound into useful chemicals is of significant industrial value. Hydrogenolysis of glycerol produces a series of C-3 alcohols, such as 1-propanol, 2-propanol, 1,2-pro-panediol and 1,3-propanediol (1,3-PDO). Among these compounds, 1,3-PDO is an important organic intermediate to synthesize poly-trimethylene-terephthalate. Therefore, synthesis of 1,3-PDO through the selective hydrogenolysis of glycerol is a promising subject. Recently, during our investigations on the Pt/WO₃/ZrO₂-catalyzed glycerol hydrolysis, it was found that the acidity of the catalyst could be controlled by tungsten oxide content and the glycerol conversion was largely improved with high 1,3-PDO selectivity. The technology largely improved the synthetic efficiency and is of potential industrial application value.

Key words: glycerol, hydrogenolysis, catalysis, biomass, 1,3-propanediol

Cite this article

Tong Qing, Gao Qiang, Xu Bolian, Yu Lei, Fan Yining. Pt/WO₃/ZrO₂-Catalyzed Selective Hydrogenolysis of Glycerol to Produce 1,3-Propanediol[J]. Chin. J. Org. Chem., 2017, 37(3): 753-758.

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Pt/WO₃/ZrO₂催化甘油选择性氢解制备1,3-丙二醇

Pt/WO₃/ZrO₂-Catalyzed Selective Hydrogenolysis of Glycerol to Produce 1,3-Propanediol

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Pt/WO3/ZrO2催化甘油选择性氢解制备1,3-丙二醇