β-Cyclodextrin Modified Gold Nanoparticles: Catalytic Applications and Molecular Selectivity

doi:10.6023/cjoc201803038

Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (11): 3002-3008.DOI: 10.6023/cjoc201803038 Previous Articles Next Articles

Special Issue: 有机小分子-金属协同催化；有机超分子化学合辑

Articles

β-环糊精修饰的金纳米粒子:催化应用及分子选择性

张薇^a, 邓维^a,b

a 上海大学材料科学与工程学院上海 200444;
b 上海应用技术大学化学与环境工程学院上海 201418

收稿日期:2018-03-25 修回日期:2018-07-03 发布日期:2018-07-24
通讯作者: 邓维 E-mail:wdeng@shu.edu.cn
基金资助:
上海市教育委员会（高原学科建设项目）、国家自然科学基金（Nos.21601125，21174081）、上海市自然科学基金（No.16ZR1435700）、上海市教育委员会双光学者（No.16SG49）、曙光学者项目及上海工业学院启动资金（No.YJ-201610）资助项目.

β-Cyclodextrin Modified Gold Nanoparticles: Catalytic Applications and Molecular Selectivity

Zhang Wei^a, Deng Wei^a,b

a School of Materials Science and Engineering, Shanghai University, Shanghai 200444;
b School of Chemical and Engineering, Shanghai Institute of Technology, Shanghai 201418

Received:2018-03-25 Revised:2018-07-03 Published:2018-07-24
Supported by:
Project supported by the Shanghai Municipal Education Commission (Plateau Discipline Construction Program), the National Science Foundation of China (Nos. 21601125, 21174081), the Natural Science Foundation of Shanghai City (No. 16ZR1435700), the Shuguang Scholar of Shanghai Municipal Education Commission (No. 16SG49), the Shuguang Scholar Project and Start-up Funding of Shanghai Institute of Technology (No. YJ-201610).

1. β-Cyclodextrin Modified Gold Nanoparticles: Catalytic Applications and Molecular Selectivity.PDF(592KB)

Abstract

L-Cys-β-CD@AuNPs nanoparticles were synthesized by a simple method of the reduction of HAuCl₄ with NaBH₄and L-Cys-CD. The catalytic activity of L-Cys-β-CD@AuNPs nanoparticles for the catalytic reductions of 4-nitrophenol and 4-nitro-1-naphthol was researched in detail. Because of the selective binding of β-cyclodextrin (β-CD) to different guest molecules, L-Cys-β-CD@AuNPs exhibits diverse catalytic activities for different substrates. The experimental results prove that L-Cys-β-CD@AuNPs shows better catalytic efficiency for the reduction of 4-nitro-1-naphthol than p-nitrophenol.

Key words: β-cyclodextrin, catalysis, gold nanoparticles, molecular selectivity, organic-inorganic hybrid materials

Cite this article

Zhang Wei, Deng Wei. β-Cyclodextrin Modified Gold Nanoparticles: Catalytic Applications and Molecular Selectivity[J]. Chin. J. Org. Chem., 2018, 38(11): 3002-3008.

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β-环糊精修饰的金纳米粒子:催化应用及分子选择性

β-Cyclodextrin Modified Gold Nanoparticles: Catalytic Applications and Molecular Selectivity

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