有机化学 ›› 2017, Vol. 37 ›› Issue (2): 335-348.DOI: 10.6023/cjoc201608030 上一篇    下一篇

所属专题: 热点论文合辑

综述与进展

过渡金属催化P-C键偶联反应的研究进展

邵长伟, 徐炜刚, 李亮, 张兴华   

  1. 上海应用技术大学化学与环境工程学院 上海 201418
  • 收稿日期:2016-08-29 修回日期:2016-09-26 发布日期:2016-10-11
  • 通讯作者: 李亮, 张兴华 E-mail:xhzhang@sit.edu.cn;lilianglcx@sit.edu.cn
  • 基金资助:

    国家自然科学基金(Nos.21302127、21502116)资助项目.

Recent Advances of Transition Metal-Catalyzed P-C Coupling Reactions

Shao Changwei, Xu Weigang, Li Liang, Zhang Xinghua   

  1. School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418
  • Received:2016-08-29 Revised:2016-09-26 Published:2016-10-11
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21302127, 21502116).

含有P-C键的有机膦化合物在光电、阻燃材料以及药物化学等研究领域具有广泛的应用.通过过渡金属催化P(O)-H化合物的交叉偶联构建P-C键是合成功能有机膦化合物的重要方法.按碳原子的不同杂化类型分类,对此类反应的研究进展进行了综述.

关键词: 过渡金属催化, P-C键, 交叉偶联

Organophosphorus compounds which contain P-C bonds have been widely used in photoelectric materials, retardant materials and medicinal chemistry. It is an important method for the synthesis of functional organophosphorus compounds from P(O)-H reagents using transition metal-catalyzed cross coupling reaction to form P-C bond. The recent development in this area is summarized on the basis of different types of carbon atom.

Key words: transition metal-catalyzed, P-C bond, cross-coupling