有机化学 ›› 2019, Vol. 39 ›› Issue (12): 3353-3362.DOI: 10.6023/cjoc201907014 上一篇    下一篇

所属专题: 有机光催化合辑

综述与进展

水相可见光催化反应研究进展

陈丹, 刘剑沉, 张馨元, 蒋合众, 李加洪   

  1. 西南交通大学生命科学与工程学院 成都 610031
  • 收稿日期:2019-07-08 修回日期:2019-08-01 发布日期:2019-08-07
  • 通讯作者: 李加洪 E-mail:jiahongljh@163.com
  • 基金资助:
    国家自然科学基金(No.21901216)、中央高校基本科研业务经费(No.2682017CX091)和2019年第十三期个性化实验(Nos.GX201913085,GX201913108)资助项目.

Recent Advances in Aqueous Phase Visible Light Catalytic Reactions

Chen Dan, Liu Jianchen, Zhang Xinyuan, Jiang Hezhong, Li Jiahong   

  1. School of Life Science and Engineering, Southwest Jiaotong University, Chengdu 610031
  • Received:2019-07-08 Revised:2019-08-01 Published:2019-08-07
  • Supported by:
    Project supported by the National Natural Science Foundation of China (No. 21901216), the Fundamental Research Funds for the Central Universities (No. 2682017CX091) and the 13th Personalized Experimental Project and the Student Research Training Program (Nos. GX201913085, GX201913108).

水作为生命体内化学反应的介质,安全、廉价、易得,具有绿色反应介质的一切特性;而可见光是一种清洁、可再生的自然资源,探索水相中光照条件下的可控自由基反应,发展绿色、高效的合成方法,不仅符合当今绿色化学主题,而且在理论和实际应用上具有重要的科学意义.对近年来水相可见光催化反应进行了综述,并对相应的机理进行了讨论.

关键词: 水相, 可见光, 自由基, 绿色化学

Water is a medium for reaction in living organisms, which is safe, cheap and easy to obtain, and visible light is a clean and renewable natural resource. Exploring the controllable free radical reaction under the illumination condition in water and developing a simple, green and efficient synthesis method not only conform to the current green chemistry theme, but also have an important scientific significance in theory and practical application. The classification and review of visible light catalysis in aqueous phase have been carried out in recent years, and the corresponding mechanisms are discussed.

Key words: water, visible light, radical, green chemistry