有机化学 ›› 2020, Vol. 40 ›› Issue (5): 1117-1128.DOI: 10.6023/cjoc201912011 上一篇    下一篇

所属专题: 有机电合成虚拟专辑 有机光催化合辑

综述与进展

光、电催化硫氰基化反应研究进展

张龙菲, 牛聪, 杨晓婷, 秦宏云, 杨建静, 文江伟, 王桦   

  1. 曲阜师范大学化学与化工学院 山东曲阜 273165
  • 收稿日期:2019-12-09 修回日期:2020-01-09 发布日期:2020-01-21
  • 通讯作者: 文江伟, 王桦 E-mail:huawang@qfnu.edu.cn;wenjy@qfnu.edu.cn
  • 基金资助:
    国家自然科学基金(Nos.21902083,21675099)、山东省重大自然科学基金(No.ZR2018ZC0129)、山东省省级大学生创新创业项目(No.S201910446044)以及曲阜师范大学科研启动基金(No.6132,6125)资助项目.

Recent Advances on the Photocatalytic and Electrocatalytic Thiocyanation Reactions

Zhang Longfei, Niu Cong, Yang Xiaoting, Qin Hongyun, Yang Jianjing, Wen Jiangwei, Wang Hua   

  1. Institute of Medicine and Materials Applied Technologies, College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, Shandong 273165
  • Received:2019-12-09 Revised:2020-01-09 Published:2020-01-21
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Nos. 21902083, 21675099), the Major Basic Research Program of Natural Science Foundation of Shandong Province (No. ZR2018ZC0129), the College Students Innovation and Entrepreneurship Training Project of Shandong Province (No. S201910446044) and the Qufu Normal University Research Startup Fund (Nos. 6132, 6125).

硫氰酸酯作为一种用途广泛的合成子,在医药、农药、材料等诸多领域中具有重要的应用价值.特别是,通过光、电催化硫氰基化反应的合成途径具有绿色、高效、安全等优势,在有机化学中得到广泛关注.重点介绍了一系列基于光、电催化的偶联/硫氰基化反应,期望为探究硫氰酸酯类化合物的绿色合成提供帮助.

关键词: 硫氰化, 光催化, 电催化

Thiocyanate, as a versatile synthon, which has important application value in many fields such as pharmaceutical, pesticide and materials. The photocatalytic and electrocatalytic thiocyanation reactions have been widely concerned in organic chemistry due to the advantages of green, efficiency and safety. In this review, the cross-coupling/thiocyanation reactions based on the photocatalytic and electrocatalytic are described, which is expected to be helpful in exploring the green synthesis of thiocyanates compounds.

Key words: thiocyanation, photocatalytic, electrocatalytic