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综述与进展

光促进十聚钨酸盐催化的C-H键官能团化反应

袁晓亚a, 杨国平b, 於兵a   

  1. a 郑州大学化学学院, 绿色催化中心 河南郑州 450001;
    b 东华理工大学江西省质谱科学与仪器重点实验室 江西南昌 330013
  • 收稿日期:2020-06-29 修回日期:2020-09-03 出版日期:2030-01-01 发布日期:2020-09-09
  • 通讯作者: 於兵 E-mail:bingyu@zzu.edu.cn
  • 基金资助:
    国家自然科学基金(No.21971224)资助项目.

Photoinduced Decatungstate-Catalyzed C-H Functionalization

Yuan Xiaoyaa, Yang Guopingb, Yu Binga   

  1. a Green Catalysis Center, College of Chemistry, Zhengzhou University, Zhengzhou 450001;
    b Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, East China University of Technology, Nanchang, 330013, China
  • Received:2020-06-29 Revised:2020-09-03 Online:2030-01-01 Published:2020-09-09
  • Supported by:
    Project supported by the National Natural Science Foundation of China (No. 21971224).

近年来,十聚钨酸盐作为催化剂在光催化有机合成领域引起了广泛关注.在光照下,十聚钨酸盐可以活化反应物中的C-H键,通过“氢原子转移”作用产生自由基,进而实现C-H键官能团化反应.本文对近年来十聚钨酸盐在光诱导下催化C-H键官能团化,构筑C-C、C-N、C-F键等的研究进展进行了综述.

关键词: 十聚钨酸盐, 氢原子转移, 光催化, 自由基, C-H键官能团化

In the recent years, the application of decatungstate[W10O32]4- as a photocatalyst for organic synthesis has drawn much attention. With the catalysis of decatungstate, the C-H bond of substrate can be converted into the corresponding radical via a hydrogen atom transfer (HAT) progress under light irradiation. In this review, we summarized the recent advances of the application of decatungstate as a photocatalyst for the C-H functionalization to construct C-C, C-N, C-F bonds.

Key words: decatungstate, hydrogen atom transfer (HAT), photocatalysis, radical, C-H functionalization