Chinese Journal of Organic Chemistry ›› 2023, Vol. 43 ›› Issue (6): 2068-2080.DOI: 10.6023/cjoc202210024 Previous Articles     Next Articles

利用硅氢加成反应催化转化二氧化碳研究进展

宋姿洁, 刘俊, 白赢*(), 厉嘉云, 彭家建*()   

  1. 杭州师范大学材料与化学化工学院 有机硅化学及材料技术教育部重点实验室 浙江省有机硅材料技术重点实验室 杭州 311121
  • 收稿日期:2022-10-22 修回日期:2022-11-25 发布日期:2023-01-05
  • 通讯作者: 白赢, 彭家建
  • 基金资助:
    浙江省自然科学基金(LY18B020012)

Progress in Catalysis Transformation of Carbon Dioxide through Hydrosilylation

Zijie Song, Jun Liu, Ying Bai*(), Jiayun Li, Jiajian Peng*()   

  1. Key Laboratory of Organosilicon Material Technology of Zhejiang Province, Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, College of Material Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121
  • Received:2022-10-22 Revised:2022-11-25 Published:2023-01-05
  • Contact: E-mail: yingbai@hznu.edu.cn; jjpeng@hznu.edu.cn
  • Supported by:
    Natural Science Foundation of Zhejiang Province(LY18B020012)

Reducing carbon dioxide emission and converting carbon dioxide from the air have always been a hot topic for researchers. Carbon dioxide is an ideal raw material for synthesizing organic compounds because of its good physical properties such as non-toxicity, abundance and easy availability. In recent years, hydrosilylation reaction has become an effective method to convert carbon dioxide into formate, formaldehyde, methanol, methane and other valuable chemical products under moderate conditions, which greatly promotes the conversion and utilization of carbon dioxide. The research progress on the design, synthesis and catalytic performance of catalytic systems used to catalyze the hydrosilylation for reduction of carbon dioxide is summarized and discussed. The reaction mechanism of hydrosilylation reduction of carbon dioxide is discussed, and the advantages and disadvantages of various catalyst systems are also analyzed. At last, the future research directions in this field are prospected.

Key words: catalysis, carbon dioxide, hydrosilylation