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有机化学
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有机化学 ›› 1998, Vol. 18 ›› Issue (4): 320-323. 上一篇    下一篇

研究论文

四(苯甲酰甲硫基)四硫富瓦烯的合成及其有关电化学性质的研究

赵富录;王小刚;王建华   

  1. 第四军医大学化学教研室;西北大学化学系
  • 发布日期:1998-08-25

The study on synthesis and electrochemical properties of tetra(benzoylmethylthio)-tetrathiafulvalene

ZHAO FULU;WANG XIAOGANG;WANG JIANHUA   

  • Published:1998-08-25

被引次数

5

本文通过4, 5-二(苯甲酰甲硫基)-1, 3-二硫杂环戊烯-2-硫酮与乙二醇反应生成其缩酮, 然后在亚磷酸三甲酯作用下偶联,最后水解, 首次成功地制得了四(苯甲酰甲硫基)四硫富瓦烯(TBMT-TTF)。用循环伏安法和UV-Vis光谱研究了有关电化学性质。为制备含羰基四硫富瓦烯提供了一条可行途径。

关键词: 甲硫基, 环戊烯 P, 亚磷酸酯类, 缩酮, 紫外分光光度法, 循环伏安法, 硫杂环化合物, 硫酮, 有机合成, 乙二醇

The reaction of 4, 5-bis(benzoylmethylthio)-1, 3-dithio-2-thione with glycol gave the ketal, followed by coupling with P(OMe)~3, and hydrolysis to give tetra (benzoylmethylthio)-tetrathiafulvalene (TBMT-TTF). The electrochemical properties of the compound have been studied by cyclic voltammetry and UV-Vis spectroscopy. The incorporating carbonyl TTF could be prepared by this method.

Key words: METHYL THIO GROUP, PHOSPHOROUS ACID ESTER, CYCLOPENTENE P, THIOKETONE, KETAL, SULFUR HETEROCYCLICS COMPOUNDS, CYCLOVOLTAMGRAPH, ETHANEDIOL, ORGANIC SYNTHESIS, ULTRAVIOLET SPECTROPHOTOMETRY

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