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有机化学
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有机化学 ›› 2007, Vol. 27 ›› Issue (07): 806-818. 上一篇    下一篇

综述与进展

铑催化不对称1,4-共轭加成反应的研究进展

王欢，杨定乔*，莫海洪   

  1. (华南师范大学化学与环境学院 广州 510006)
  • 收稿日期:2006-07-26 修回日期:1900-01-01 发布日期:2007-06-30
  • 通讯作者: 杨定乔*，

Progress in Rhodium-Catalyzed Asymmetric 1,4-ConjugateAddition Reactions

WANG Huan,YANG Ding-Qiao*,MO Hai-Hong   

  1. (School of Chemistry and Environment, South China Normal University, Guangzhou 510006)
  • Received:2006-07-26 Revised:1900-01-01 Published:2007-06-30
  • Contact: YANG Ding-Qiao*

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被引次数

2 | 1

铑催化不对称1,4-共轭加成反应是一种非常有效的碳-碳键形成方法. 本文综述了近年来铑催化不对称1,4-共轭加成反应的研究进展, 包括α,β-不饱和酮、酯、酰胺、醛和砜等与某些亲核试剂的1,4-共轭加成反应.

关键词: 铑催化, 不对称, 1,4-共轭加成, 亲核试剂

Rhodium-catalyzed asymmetric 1,4-conjugate addition reaction is one of the most efficient methods for the carbon-carbon bond formation. In this paper, the recent progress in rhodium-catalyzed asymmetric 1,4-conjugate addition reactions is reviewed. Asymmetric 1,4-conjugate additions of α,β-unsaturated ketones, esters, amides, aldehydes, sulfones and so on with some nu-cleophiles are presented.

Key words: 1,4-conjugate addition, asymmetric, nucleophile, rhodium-catalyzed