有机化学 ›› 2007, Vol. 27 ›› Issue (9): 1087-1095. 上一篇    下一篇

综述与进展

含有手性连接基的双噁唑啉配体及其在不对称催化反应中的应用

张佳明,张勇健,张万斌*   

  1. (上海交通大学化学化工学院 上海 200240)
  • 收稿日期:2006-08-10 修回日期:2007-01-10 发布日期:2007-08-30
  • 通讯作者: 张万斌*

Bisoxazoline Ligands with Chiral Backbones and Their Applications in Asymmetric Catalytic Reactions

ZHANG Jia-Ming,ZHANG Yong-Jian,ZHANG Wan-Bin*   

  1. School of Chemistry & Chemical Technology, Shanghai Jiaotong University, Shanghai 200240 )
  • Received:2006-08-10 Revised:2007-01-10 Published:2007-08-30
  • Contact: ZHANG Wan-Bin*

综述了具有手性连接基的双噁唑啉配体及其主要类型, 并介绍了它们参与的不对称催化反应.

关键词: 双噁唑啉配体, 中心手性, 手性连接基, 面手性, 轴手性, 不对称催化

Bisoxazoline ligands with different kinds of chiral backbones are introduced, and their applications in asymmetric catalytic reactions are described.

Key words: axial chiralty, planar chiralty, asymmetric catalys, chiral backbone, center chiralty, bisoxazoline ligand