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有机化学
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有机化学 ›› 2005, Vol. 25 ›› Issue (08): 997-1000. 上一篇    下一篇

研究简报

2,5-二[4-(2-芳基乙烯基)苯基]噁二唑的合成及发光特征

张田林*，李海虹，原中立   

  1. (1淮海工学院化工系 连云港 222005)
    (2 716研究所 连云港 222005)
  • 收稿日期:2004-12-23 修回日期:2005-02-17 发布日期:2005-07-30
  • 通讯作者: 张田林

Synthesis and Light-emitting Characters of 2,5-Bis[4- (2-arylvinyl)phenyl]-1,3,4-oxadiazoles

ZHANG Tian-Lin*,LI Hai-Hong,YUAN Zhong-Li   

  1. (1 Department of Chemical Technology, Huaihai Institute of Technology, Lianyungang 222005)
    (2 716 Institute, Lianyungang 222005)
  • Received:2004-12-23 Revised:2005-02-17 Published:2005-07-30
  • Contact: ZHANG Tian-Lin

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被引次数

12

二乙烯联苯及其衍生物是一种可发射蓝光的小分子空穴型有机发光材料, 通过Wittig-Horner反应, 将电子传输型噁二唑环“嵌入”其中, 设计合成了6个2,5-二[4-(2-芳基乙烯基)苯基]-1,3,4-噁二唑化合物. 经光谱分析和元素分析等方法确认了它们的化学结构. IR和UV-vis分析数据表明标题化合物分子结构中的C＝C双键均为反式结构特征. 研究结果表明: 2,5-二[4-(2-对二甲氨基苯基乙烯基)苯基]-1,3,4-噁二唑具有良好的蓝色发光性能; 取代基对标题化合物的UV-vis吸收光谱和发光特性的影响显着.

关键词: 2,5-二[4-(2-芳基乙烯基)苯基]-1,3,4-噁二唑, 电致发光, Wittig-Horner反应, 有机合成, 蓝色发光

Six novel 2,5-bis[4-(2-arylvinyl)phenyl]-1,3,4-oxadiazoles were designed and synthesized through Wittig-Horner reaction by embedding electron-transporting 1,3,4-oxadiazole in PPV oligomer, which are one kind of blue luminescence materials with highly hole injection, and their chemical structures were also determined to show trans-vinylene character according to IR and 1H NMR spectra. The analytic results showed that 2,5-bis{4-[2-(p-dimethylaminophenyl)vinyl]phenyl}-1,3,4-oxadiazole has good blue light-emitting property and the substitutes have significant effects on the UV-vis and PL/EL spectra.

Key words: electroluminescence, 2,5-bis[4-(2-arylvinyl)phenyl]-1,3,4-oxadiazole, Wittig-Horner reaction, organic synthesis, blue light-emitting