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有机化学
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有机化学 ›› 2008, Vol. 28 ›› Issue (07): 1169-1180. 上一篇    下一篇

综述与进展

轴不稳定手性配体的开发及其在不对称催化反应中的应用

戴轶俊 ; 杨国强; 张勇健 ; 王飞军; 张万斌*   

  1. (上海交通大学化学化工学院 上海 200240)
  • 收稿日期:2007-09-05 修回日期:2007-12-04 发布日期:2008-07-28
  • 通讯作者: 张万斌

Development of Axial-unfixed (Tropos) Ligands and Their Applications to Asymmetric Catalytic Reactions

DAI, Yi-Jun; YANG, Guo-Qiang ; ZHANG, Yong-Jian; WANG, Fei-Jun ; ZHANG, Wan-Bin*
  

  1. (School of Chemistry & Chemical Technology, Shanghai Jiaotong University, Shanghai 200240)
  • Received:2007-09-05 Revised:2007-12-04 Published:2008-07-28
  • Contact: ZHANG, Wan-Bin

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被引次数

8 | 3

轴不稳定配体应用于不对称催化有其独到的特点, 不同于传统的轴稳定手性配体. 综述了轴不稳定的噁唑啉、双膦、单膦、双羟基及N—O等配体的开发及其在不对称催化中的应用.

关键词: 轴手性, 轴不稳定配体, 不对称催化

Tropos ligands, compared with traditional atropos ligands, have unique characteristics. Here, the development of several major types of tropos ligands, including oxazoline, biphosphine, monophosphine, bihydroxyl and N—O ligands, and their applications to asymmetric catalysis are reviewed.

Key words: axial-unfixed ligand, asymmetric catalysis, axial chirality