简单易得试剂与磷-氢化合物交叉偶联合成有机磷化合物

doi:10.6023/cjoc201702050

有机化学 ›› 2017, Vol. 37 ›› Issue (5): 1055-1068.DOI: 10.6023/cjoc201702050 上一篇下一篇

综述与进展

简单易得试剂与磷-氢化合物交叉偶联合成有机磷化合物

杨佳^a, 肖晶^a,c, 周永波^a, 陈铁桥^a, 尹双凤^a, 韩立彪^b

a 湖南大学化学化工学院化学生物传感与计量学国家重点实验室长沙 410082;
b National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8565, Japan;
c 湖南科技大学理论有机化学与功能分子教育部重点实验室湘潭 411201

收稿日期:2017-02-28 修回日期:2017-04-08 发布日期:2017-05-02
通讯作者: 周永波,韩立彪 E-mail:zhouyb@hnu.edu.cn;libiao-han@aist.go.jp
基金资助:
国家自然科学基金（Nos.21373080，21573065，21273066）和湖南省杰出青年基金（No.2016JJ1007）资助项目.

Recent Advances in the Synthesis of Organophosphorus Compounds via Cross Coupling between Readily Available Materials and P-H Compounds

Yang Jia^a, Xiao Jing^a,c, Zhou Yongbo^a, Chen Tieqiao^a, Yin Shuangfeng^a, Han Libiao^b

a State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082;
b National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8565, Japan;
c Key Laboratory of Theoretical Organic Chemistry and Functional Molecule of the Ministry of Education, Hunan University of Science and Technology, Xiangtan 411201

Received:2017-02-28 Revised:2017-04-08 Published:2017-05-02
Contact: 10.6023/cjoc201702050 E-mail:zhouyb@hnu.edu.cn;libiao-han@aist.go.jp
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21373080, 21573065, 21273066), and the Natural Science Foundation of Hunan Province (No. 2016JJ1007)

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摘要/Abstract

综述了近年来利用磷-氢化合物与简单易得试剂交叉偶联合成有机磷化合物的研究进展.主要包括利用末端炔烃与磷-氢化合物通过C-H/P-H交叉偶联合成炔基膦化合物，利用简单易得的含氧、含硫或含氮有机化合物与磷-氢化合物交叉偶联构建sp²/sp³-C-P键或P-Z键，并对部分反应的机理进行扼要总结．

关键词: 磷-氢化合物, 交叉偶联, 有机磷化合物

This mini-review focuses on the recent advances in the synthesis of organophosphorus compounds via cross coupling of P-H compounds with readily available starting materials, mainly including the reactions of terminal alkynes and heteroatom compounds (oxygen, sulfur or nitrogen-contained compounds) with P-H compounds forming sp-C-P, sp²-C-P, sp³-C-P, and P-Z bonds. Related reaction mechanisms are also discussed.

Key words: P-H compounds, cross coupling, organophosphorus compounds

引用此文

杨佳, 肖晶, 周永波, 陈铁桥, 尹双凤, 韩立彪. 简单易得试剂与磷-氢化合物交叉偶联合成有机磷化合物[J]. 有机化学, 2017, 37(5): 1055-1068.

Yang Jia, Xiao Jing, Zhou Yongbo, Chen Tieqiao, Yin Shuangfeng, Han Libiao. Recent Advances in the Synthesis of Organophosphorus Compounds via Cross Coupling between Readily Available Materials and P-H Compounds[J]. Chin. J. Org. Chem., 2017, 37(5): 1055-1068.

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简单易得试剂与磷-氢化合物交叉偶联合成有机磷化合物

Recent Advances in the Synthesis of Organophosphorus Compounds via Cross Coupling between Readily Available Materials and P-H Compounds

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