New Advances in Palladium-Catalyzed Aerobic Oxidations

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Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (04): 397-412. Next Articles

Review

Pd催化的需氧氧化反应的新进展

王嘉瑞，邓维，王晔峰，刘磊，郭庆祥*

(中国科学技术大学化学系合肥 230026)

收稿日期:2005-01-10 修回日期:2005-08-30 发布日期:2006-03-31
通讯作者: 郭庆祥

New Advances in Palladium-Catalyzed Aerobic Oxidations

WANG Jia-Rui,DENG Wei,WANG Ye-Feng,LIU Lei,GUO Qing-Xiang*

(Department of Chemistry, University of Science and Technology of China, Hefei 230026)

Received:2005-01-10 Revised:2005-08-30 Published:2006-03-31

Contact: GUO Qing-Xiang

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Abstract

New advances in palladium-catalyzed aerobic oxidation reactions are reviewed. The reactions include aerobic oxidation of alcohol, kinetic resolution of secondary alcohols, oxidation of alkenes, oxidative C—O, C—N and C—C bond formation reactions, oxidative ring opening, expansion and contracting reactions. In addition, the mechanisms of these novel reactions are discussed in detail

Key words: catalyst, kinetic resolution, aerobic oxidation, molecule oxygen, palladium

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WANG Jia-Rui,DENG Wei,WANG Ye-Feng,LIU Lei,GUO Qing-Xiang*. New Advances in Palladium-Catalyzed Aerobic Oxidations[J]. Chin. J. Org. Chem., 2006, 26(04): 397-412.

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[1]	Shuang Yang, Xinqiang Fang. Kinetic Resolutions Enabled by N-Heterocyclic Carbene Catalysis: An Update [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 448-480.
[2]	Xianqiang Meng, Yi Yang, Wanjie Liang, Jingtao Wang, Rongkui Zhang, Hui Liu. Palladium-Catalyzed Regioselective Aryl Phenoxylation of Allenamide [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 224-231.
[3]	Qianfan Zhao, Yongzheng Chen, Shiming Zhang. Application and Mechanism Study of Carbon-Based Metal-Free Catalysts in Organic Synthesis [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 137-147.
[4]	Hao Qin, Chuanjin Hou, Dinghua Liang, Xinwei He, Ling Li, Xiangping Hu. Chiral P,N,N-Ligands for Pd-Catalyzed Asymmetric Allylic Substitutions [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 282-290.
[5]	Jianghu Dong, Liangming Xuan, Chi Wang, Chenxi Zhao, Haifeng Wang, Qiongjiao Yan, Wei Wang, Fen'er Chen. Recent Advances in Visible-Light-Induced C(3)—H Functionalization of Quinoxalinones under Transition-Metal-Free or Photocatalyst-Free [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 111-136.
[6]	Jingrui Wang, Yongkui Feng, Nengzhong Wang, Nianyu Huang, Hui Yao. Pd-Catalyzed Stereoselective Synthesis of Nitroalkyl β-C-Glycosides [J]. Chinese Journal of Organic Chemistry, 2023, 43(9): 3216-3225.
[7]	Huijuan Hu, Qiaoli Yan, Xiaogang Lu, Qifan Yang, Chengxin Pei, Hongmei Wang, Runli Gao. Kinetic Resolution of Racemic P-Chiral α-Hydroxymethylphos-phonates Catalyzed by Lipase from Porcine Pancreas [J]. Chinese Journal of Organic Chemistry, 2023, 43(8): 2815-2825.
[8]	Yuchao Wang, Jinbiao Liu, Zhitao He. Palladium-Catalyzed Asymmetric Hydrofunctionalizations of Conjugated Dienes [J]. Chinese Journal of Organic Chemistry, 2023, 43(8): 2614-2627.
[9]	Kai Lu, Haoqi Qu, Xi Chen, Hui Qiu, Jing Zheng, Mengtao Ma. Catalyst-Free and Solvent-Free Hydroboration of Alkynes and Alkenes with Catecholborane [J]. Chinese Journal of Organic Chemistry, 2023, 43(6): 2197-2205.
[10]	Yangyang Chu, Zhaobin Han, Kuiling Ding. Progresses in the Application of Kinetic Resolution in Transition Metal Catalyzed Asymmetric (Transfer) Hydrogenation [J]. Chinese Journal of Organic Chemistry, 2023, 43(6): 1934-1951.
[11]	Cheng Luo, Yanli Yin, Zhiyong Jiang. Recent Advances in Asymmetric Synthesis of P-Chiral Phosphine Oxides [J]. Chinese Journal of Organic Chemistry, 2023, 43(6): 1963-1976.
[12]	Baichuan Mo, Chunxia Chen, Jinsong Peng. Research Progress in Application of Lignin and Its Derivatives Supported Metal Catalysts in Organic Synthesis [J]. Chinese Journal of Organic Chemistry, 2023, 43(4): 1215-1240.
[13]	Yuliang Chen, Fengkai He, Siyun Wang, Dingcheng Jia, Yaqun Liu, Yiyong Huang. Kinetic Resolution of Aldehydes Bearing an All-Carbon Quaternary Stereocenter at the α-Position by the Antilla Allylboration [J]. Chinese Journal of Organic Chemistry, 2023, 43(12): 4294-4302.
[14]	Meijiao Sun, Jing Tan, Yu Tan, Jinsong Peng, Chunxia Chen. Pd-Catalyzed C(2)—H Arylation of 3-(2-Aminopyrimidin-4-yl)indoles [J]. Chinese Journal of Organic Chemistry, 2023, 43(11): 3945-3959.
[15]	Tiantian Liu, Xinhong Duan. Recent Progress in the Construction of Chiral 3-Substituted Indoles by Asymmetric Friedel-Crafts Reactions [J]. Chinese Journal of Organic Chemistry, 2023, 43(11): 3695-3712.