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综述与进展

可见光促进烷基硼化合物转化研究进展

史敦发a,b, 王露a, 夏春谷a, 刘超a   

  1. a 中国科学院兰州化学物理研究所 羰基合成与选择氧化国家重点实验室 兰州 730000;
    b 中国科学院大学 北京 100049
  • 收稿日期:2020-06-18 修回日期:2020-08-29 出版日期:2030-01-01 发布日期:2020-09-09
  • 通讯作者: 刘超 E-mail:chaoliu@licp.cas.cn
  • 基金资助:
    国家自然科学基金(No.21673261,91745110,21872156),江苏省自然科学基金项目(No.BK20190002,BK20181194),中科院青年创新促进会项目(No.2018458).

Recent Advances in Photoinduced Transformation of Alkyl Boron Compounds

Shi Dunfaa,b, Wang Lua, Xia Chungua, Liu Chaoa   

  1. a State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000;
    b University of Chinese Academy of Sciences, Beijing, 100049
  • Received:2020-06-18 Revised:2020-08-29 Online:2030-01-01 Published:2020-09-09
  • Supported by:
    Project supported by the National Natural Science Foundation of China (No. 21673261, 91745110, 21872156), Natural Science Foundation of Jiangsu Province (No. BK20190002, BK20181194), the Youth Innovation Promotion Association CAS (No. 2018458).

有机硼化合物来源广泛,转化丰富多样,已经成为一种重要的有机合成中间体并且被广泛地应用于医药、农药以及有机光电材料的合成中。烷基硼化合物作为一类重要的有机硼化合物,其合成以及转化研究具有重要意义。可见光近来在有机反应领域受到广泛关注。在可见光诱导下,四配位烷基硼化合物能发生单电子转移产生烷基自由基,从而进一步构建不同的化学键。本文综述了该研究领域的相关进展。

关键词: 硼, 光催化, 自由基, 单电子转移

Organoboron compounds are valuable synthetic intermediates and widely used in the synthesis of medicine, pesticide and organic optoelectronic materials due to their extensive resouce and highly transformable ability. Among various organoboron compounds,the synthesis and transformation of alkylboron compounds have attracted much attention. As a sustainable and green energy, visible light shows an important effect in organic systhesis. Tetracoordinated alkylboron compounds could occur single electron transfer (SET) process to generate alkyl radical for further transformations. Herein, recent advances in the photoinduced transformation of alkyl boron compounds have been summarized.

Key words: Boron, photocatalysis, radical, single electron transfer