有机化学 ›› 2014, Vol. 34 ›› Issue (4): 693-705.DOI: 10.6023/cjoc201309039 上一篇    下一篇

综述与进展

联吡啶金属配合物在偶联反应中的应用

李英俊, 李志朋, 李兴, 常宏宏, 魏文珑   

  1. 太原理工大学化学化工学院生物与制药工程系 太原 030024
  • 收稿日期:2013-09-27 修回日期:2013-11-19 发布日期:2013-12-13
  • 通讯作者: 魏文珑 E-mail:weiwenlong@tyut.edu.cn
  • 基金资助:

    山西省自然科学基金(Nos. 2012021007-2,2011011010-2)及山西省高等教育机构科技创新项目基金(No. 20120006)资助项目.

Application of Bipyridyl Complexes in Coupling Reactions

Li Yingjun, Li Zhipeng, Li Xing, Chang Honghong, Wei Wenlong   

  1. College of Chemistry and Chemical Engineering, Taiyuan University of Teconology, Taiyuan 030024
  • Received:2013-09-27 Revised:2013-11-19 Published:2013-12-13
  • Supported by:

    Project supported by the Natural Science Foundation of Shanxi Province (Nos. 2012021007-2, 2011011010-2) and the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi Province (No. 20120006).

联吡啶类配体具有超强的氧化还原稳定性和结构易修饰的性质,被广泛地用于合成金属螯合配合物或直接当作配体使用,在有机合成中的应用也变的越来越重要. 主要从C—C,C—N,C—S,C—O和C—Se键的形成角度概括了联吡啶配体在各种偶联反应中应用的研究进展.

关键词: 联吡啶金属配合物, 偶联, C—C键, C—N键, C—S键, C—O键, C—Se键

The bipyridyl ligands have been extensively used as metal chelating complexes or directly utilized as ligands due to their robust redox stability and ease of functionalization which also become more and more important in the application of the organic synthesis. This article mainly describes the application of bipyridyl complexes in coupling reactions for the formation of C—C, C—N, C—S, C—O and C—Se bonds.

Key words: bipyridyl complex, coupling, C—C bond, C—N bond, C—S bond, C—O bond, C—Se bond