有机化学 ›› 2021, Vol. 41 ›› Issue (6): 2202-2216.DOI: 10.6023/cjoc202011034 上一篇    下一篇

综述与进展

有机转化中二碘化钐及其他钐试剂近期发展研究

刘晨, 齐燕*(), 刘永军*()   

  1. 青岛科技大学化学与分子工程学院 光电传感与生命分析教育部重点实验室 青岛 266042
  • 收稿日期:2020-11-25 修回日期:2021-01-28 发布日期:2021-02-26
  • 通讯作者: 齐燕, 刘永军
  • 基金资助:
    山东省重点研发计划(2019GGXI02036)

Recent Development of Samarium Diiodide and Other Samarium Reagents in Organic Transformation

Chen Liu, Yan Qi(), Yongjun Liu()   

  1. Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, Ministry of Education, College of Chemistry and Molecular Engineering, Qingdao University of Science & Technology, Qingdao 266042
  • Received:2020-11-25 Revised:2021-01-28 Published:2021-02-26
  • Contact: Yan Qi, Yongjun Liu
  • Supported by:
    Shandong Provincial Key Research and Development Program(2019GGXI02036)

钐试剂自被发现以来, 一直在有机合成中占据着一席之地. SmI2优异的单电子转移能力和还原能力都具有重要的研究价值. Sm、allylSmBr、SmI3等其他钐试剂的潜力也逐渐被开发出来. 综述了近5年来SmI2以及其他钐试剂介入的反应. 主要分为三大部分: (1) SmI2促进的偶联反应研究, (2)其他钐试剂(Sm, allylSmBr, SmI3, Sm(OTf)3)等促进的偶联反应研究, (3)钐试剂介入的有机还原反应.

关键词: 有机合成, 偶联反应, 还原反应, 二碘化钐, 钐试剂, 有机钐

Since the samarium diiodide was discovered, it has been occupying a key field in organic synthesis due to the excellent ability of both single electron transfer and reduction. Other samarium reagents have also been wildly developed in recent years, such as Sm, allylSmBr, SmI3and so on. In this review, the reactions mediated by samarium reagents especially SmI2 in latest five years are summarized. It mainly includes three parts: studies on the SmI2 promoted coupling reactions, studies on the coupling reactions promoted by other samarium reagents (Sm, allylSmBr, SmI3, Sm(OTf)3 etc.), and studies on the samarium reagents promoted organic reduction reactions.

Key words: organic synthesis, coupling reactions, reductions, samarium diiodide, samarium reagents, organosamarium