单原子光催化有机合成研究进展

doi:10.6023/cjoc202407042

综述与进展

单原子光催化有机合成研究进展

吴利华^a,&, 杨建静^a,&, 闫克鲁^a, 许丽荣^a, 文江伟^a,*

^a山东省绿色天然产物与医药中间体重点实验室,曲阜师范大学化学与化工学院,曲阜 273165

收稿日期:2024-07-28 修回日期:2024-09-17
基金资助:
山东省自然科学基金(No. ZR2020QB130),曲阜师范大学人才启动基金(No. 6125, 6132).

Advancing Single-atom Photocatalysis in Organic Synthesis

Lihua Wu^a,&, Jianjing Yang^a,&, Kelu Yan^a, Lirong Xu^a, Jiangwei Wen^a,*

^aKey Laboratory of Green Natural Products and Pharmaceutical Intermediates in Colleges and Universities of Shandong Province, School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, 2763165, P. R. China

Received:2024-07-28 Revised:2024-09-17
Contact: * E-mail: wenjy@qfnu.edu.cn
About author:^&These authors contributed equally to this work.
Supported by:
Natural Science Foundation of Shandong Province (No. ZR2020QB130), and Foundation of Qufu Normal University (NO. 6132 and 6125).

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摘要/Abstract

单原子光催化剂具有高表面积、优异的催化活性和选择性,有助于提高反应效率并减少副反应的产生,其催化机理易于理解,在有机合成反应中展现出独特的潜力。此外,单原子光催化还具有优异的可回收利用性能,是一种新颖的绿色催化策略,为有机光催化合成化学提供独特的机会。尽管单原子光催化在多个领域中均已获得广泛关注,而在有机合成研究领域中的应用仍较少,且缺乏系统性总结。为了让读者能够快速了解该研究领域的进展,本文根据成键类型C-C键和C-X (X = N, O, S, P, B等)系统性综述了近十年来单原子光催化在有机合成应用中的进展。此外,对底物范围和机理进行了讨论,旨在为开发新的单原子光催化有机合成方法奠定基础。

关键词: 单原子, 光催化, 有机合成

The single atom photocatalyst exhibits a large surface area, exceptional catalytic activity, and selectivity, thereby enhancing reaction efficiency and minimizing the occurrence of side reactions. Its catalytic mechanism is easily comprehensible, rendering it uniquely promising for organic synthesis reactions. The single-atom photocatalysis, in addition to its excellent recyclability, represents a novel and environmentally friendly catalytic strategy that offers unique opportunities for organic photocatalytic synthesis chemistry. Although single-atom photocatalysis has received widespread attention in many fields, its application in organic synthesis research is still relatively rare and lacks a systematic summary. In order to enable readers to quickly understand the progress in this field, the present review provides a comprehensive overview of the applications of single atom photocatalysts in various organic synthesis reactions over the past decade, classified according to bond formation involving C-C and C-X (X = N, O, S, P, B, etc.). Moreover, this review also elucidates the application range and underlying mechanisms involved in these reactions, aiming to lay the foundation for the development of new single-atom photocatalytic organic synthesis methods.

Key words: Single atom, Photocatalysis, Organic synthesis

引用此文

吴利华, 杨建静, 闫克鲁, 许丽荣, 文江伟. 单原子光催化有机合成研究进展[J]. 有机化学, doi: 10.6023/cjoc202407042.

Lihua Wu, Jianjing Yang, Kelu Yan, Lirong Xu, Jiangwei Wen. Advancing Single-atom Photocatalysis in Organic Synthesis[J]. Chinese Journal of Organic Chemistry, doi: 10.6023/cjoc202407042.

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