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封面介绍The recent research progress in the synthesis of organo-silicons by copper-catalyzed silyl addition of silyl rea-gents to diverse unsaturated compounds such as α,β- unsaturated carbonyl compounds, imines, Morita-Baylis- Hillman (MBH) alcohols, p-quinone methides, α,β-unsa- turated alkyne carbonyl compounds and α,β-unsaturated sulfones is summarized by Han, Li, Chen, Zhang, Zhao, Zhang, and Zhu on page 555. It will largely promote the development of such copper-catalyzed silyl addition reactions. -
封面介绍The synthesis of α-aryl nitriles via nucleophilic sub- stitution of α-cyanohydrin methanesulfonates with malo- nates is reported by Wang, Zheng, Zhou, Wang, Yan, Wang and Chen on page 668. This transition metal-free protocol has the advantages of cheap and easily avai- lable starting materials, mild reaction conditions, simple operation, a broad substrate scope and high functional group tolerance. Furthermore, this strategy could also be used to asymmetric malonates and acyl esters. -
封面介绍The recent progress in selective C—F bond activation of trifluoromethyl akenes is reviewed by Xu and Song on page 411. The research progress in this area is summa-rized, including nucleophilic addition/defluorination (SN2' type), acid-promoted defluorinative Friedel-Crafts arylation, (formal) ipso-defluorinative functionalization, and transition-metal-catalyzed migratory insertion/de- fluorination. Finally, the future direction in this area is also prospected. -
封面介绍One feasible methodology has been developed for oxi-dative cross-coupling between quinoxalinones and pyr-roles. Mechanism studies show that electron-rich pyrroles own nearly ten times quenching rate constant than that of electron-deficient quinoxalinones. Utilizing the commerial available photocatalyst Mes-Acr-Me+ClO-4(3 mol%), the oxidative coupling products of quinolones and pyrrole derivatives have been synthesized by Shen, Li, Zhou, Wang and Wang on page 697.
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本期栏目
目录
综述与进展
有机化学
2023, 43 (2), pp 379-410
DOI: 10.6023/cjoc202207015
有机化学
2023, 43 (2), pp 411-425
DOI: 10.6023/cjoc202210016
有机化学
2023, 43 (2), pp 426-435
DOI: 10.6023/cjoc202208028
有机化学
2023, 43 (2), pp 436-454
DOI: 10.6023/cjoc202208020
有机化学
2023, 43 (2), pp 455-470
DOI: 10.6023/cjoc202208008
有机化学
2023, 43 (2), pp 471-490
DOI: 10.6023/cjoc202206054
有机化学
2023, 43 (2), pp 491-502
DOI: 10.6023/cjoc202207029
有机化学
2023, 43 (2), pp 503-525
DOI: 10.6023/cjoc202206006
有机化学
2023, 43 (2), pp 526-554
DOI: 10.6023/cjoc202204010
有机化学
2023, 43 (2), pp 555-572
DOI: 10.6023/cjoc202207043
有机化学
2023, 43 (2), pp 573-601
DOI: 10.6023/cjoc202207042
有机化学
2023, 43 (2), pp 602-621
DOI: 10.6023/cjoc202207027
研究论文
有机化学
2023, 43 (2), pp 622-628
DOI: 10.6023/cjoc202206033
有机化学
2023, 43 (2), pp 629-635
DOI: 10.6023/cjoc202206047
有机化学
2023, 43 (2), pp 636-645
DOI: 10.6023/cjoc202207001
有机化学
2023, 43 (2), pp 646-659
DOI: 10.6023/cjoc202207033
有机化学
2023, 43 (2), pp 660-667
DOI: 10.6023/cjoc202203012
有机化学
2023, 43 (2), pp 668-678
DOI: 10.6023/cjoc202208029
有机化学
2023, 43 (2), pp 679-685
DOI: 10.6023/cjoc202203031
有机化学
2023, 43 (2), pp 686-696
DOI: 10.6023/cjoc202206030
有机化学
2023, 43 (2), pp 697-704
DOI: 10.6023/cjoc202207031
有机化学
2023, 43 (2), pp 705-711
DOI: 10.6023/cjoc202207007
有机化学
2023, 43 (2), pp 712-717
DOI: 10.6023/cjoc202206007
有机化学
2023, 43 (2), pp 718-724
DOI: 10.6023/cjoc202205019
有机化学
2023, 43 (2), pp 725-733
DOI: 10.6023/cjoc202207038
有机化学
2023, 43 (2), pp 734-741
DOI: 10.6023/cjoc202207021
有机化学
2023, 43 (2), pp 742-750
DOI: 10.6023/cjoc202207032
研究简报
有机化学
2023, 43 (2), pp 751-755
DOI: 10.6023/cjoc202208019
有机化学
2023, 43 (2), pp 756-762
DOI: 10.6023/cjoc202206023
有机化学
2023, 43 (2), pp 763-770
DOI: 10.6023/cjoc202206048
有机化学
2023, 43 (2), pp 771-776
DOI: 10.6023/cjoc202207005
有机化学
2023, 43 (2), pp 777-780
DOI: 10.6023/cjoc202207030
亮点述评
有机化学
2023, 43 (2), pp 781-782
DOI: 10.6023/cjoc202300007
有机化学
2023, 43 (2), pp 783-785
DOI: 10.6023/cjoc202300008
有机化学
2023, 43 (2), pp 786-788
DOI: 10.6023/cjoc202300009
有机化学
2023, 43 (2), pp 789-790
DOI: 10.6023/cjoc202300010
